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Ta có: \(n_{H_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
a, \(n_{Fe}=n_{H_2}=0,45\left(mol\right)\Rightarrow m_{Fe}=0,45.56=25,2\left(g\right)\)
b, \(n_{HCl}=2n_{H_2}=0,9\left(mol\right)\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,9}{0,15}=6\left(M\right)\)
c, \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
\(4Fe\left(OH\right)_2+O_2\underrightarrow{t^o}2Fe_2O_3+4H_2O\)
Theo PT: \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_2}=\dfrac{1}{2}n_{FeCl_2}=\dfrac{1}{2}n_{H_2}=0,225\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,225.160=36\left(g\right)\)
\(m_{NaOH}=\dfrac{200\cdot8}{100}=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4mol\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
0,4 0,4 0,4 0,4
a)\(m_{HCl}=0,4\cdot36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3}\cdot100=200\left(g\right)\)
b)\(m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)
\(m_{H_2O}=0,4\cdot18=7,2\left(g\right)\)
\(m_{ddsau}=200+200-7,2=392,8\left(g\right)\)
\(\Rightarrow C\%=\dfrac{23,4}{392,8}\cdot100=5,96\%\)
c) \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(2NaOH+SO_2\rightarrow Na_2SO_4+H_2O\)
0,4 0,3 0,3 0,3
\(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH :
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,15 0,3 0,15 0,15
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
0,1 0,6 0,2 0,3
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
\(m_{Fe_2O_3}=15-8,4=6,6\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(C_{M\left(HCl\right)}=\dfrac{0,3+0,6}{0,05}=18\left(M\right)\)
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
0,35 0,35
\(m_{Fe\left(OH\right)_2}=0,35.90=31,5\left(g\right)\)
\(a,n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1mol\\ Na_2SO_3+2HCl\rightarrow2NaCl+SO_2+H_2O\\ n_{SO_2}=n_{Na_2SO_4}=0,1mol\\ V_{SO_2}=0,1.22,4=2,24l\\ b,n_{HCl}=0,1.2=0,2mol\\ C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\\ c,n_{NaOH}=\dfrac{40.10}{100.40}=0,1mol\\ T=\dfrac{0,1}{0,1}=1\\ \Rightarrow Tạo,NaHSO_3\\ NaOH+SO_2\rightarrow NaHSO_3\\ m_{NaHSO_3}=0,1.64+0,1.40=10,4g\)
