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Sửa đề cho dễ làm : dd K2CO3 13,8%
PTHH: \(2CH_3COOH+K_2CO_3\rightarrow2CH_3COOK+H_2O+CO_2\uparrow\)
a+b) Ta có: \(n_{CH_3COOH}=\dfrac{150\cdot12\%}{60}=0,3\left(mol\right)\)
\(\Rightarrow n_{K_2CO_3}=n_{CO_2}=0,15\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddK_2CO_3}=\dfrac{0,15\cdot138}{13,8\%}=150\left(g\right)\\V_{CO_2}=0,15\cdot22,4=3,36\left(l\right)\end{matrix}\right.\)
c) Theo PTHH:: \(n_{CH_3COOK}=0,3\left(mol\right)\) \(\Rightarrow m_{CH_3COOK}=0,3\cdot98=29,4\left(g\right)\)
Mặt khác: \(m_{CO_2}=0,15\cdot44=6,6\left(g\right)\)
\(\Rightarrow m_{dd}=m_{ddCH_3COOH}+m_{ddK_2CO_3}-m_{CO_2}=293,4\left(g\right)\)
\(\Rightarrow C\%_{CH_3COOK}=\dfrac{29,4}{293,4}\cdot100\%\approx10,02\%\)
\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)
a) \(n_{CH_3COOH}=\dfrac{120.20\%}{60}=0,4\left(mol\right)\)
\(n_{Na_2CO_3}=\dfrac{53.30\%}{106}=0,15\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\) => Na2CO3 hết, CH3COOH dư
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,15-------->0,3-------------->0,3------->0,15
=> \(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\)
b) mdd sau pư = 120 + 53 - 0,15.44 = 166,4 (g)
=> \(C\%=\dfrac{24,6}{166,4}.100\%=14,78\text{%}\)
\(a)n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ n_{Mg}=\dfrac{4,8}{24}=0,2mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(V_{H_2}=\left(0,1+0,2\right).22,4=6,72l\\ b)V_{ddHCl}=\dfrac{0,2+0,4}{2}=0,3l\\ c)m_{muối}=0,1.127+95.0,2=31,7g\)
Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)
Ta có: \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)
\(\%m_{Zn}=100\%-30,11\%=69,89\%\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4
\(n_{HCl}=0,2+0,4=0,6mol\)
\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)
gọi kim loại ht 2 là X hóa trị 3 là Y nX=a ; nY=b
pthh
X+2HCl--->XCl2+H2
a 2a a a
2Y+6HCl--->2YCl3+3H2
b 3b b 1,5b
theo pthh => 2a+3b=n HCl=0,34 mol
gọi khối lượng mol của X là X của Y là Y
a, khối lượng muối=(X+71).a +(Y+106,5).b=Xa+Yb+35,5.(2a+3b)
=4+12,07=16,07 g
b, theo pthh thì n H2=1/2 n HCl=0,17 mol
=> V H2=3,808 l
nZn = 3,25/65=0,05 mol
2Zn + 2CH3COOH --> 2CH3COOZn + H2
0,05 0,05 0,05 0,025 mol
=> VH2= 0,025*22,4=0,56 lít
mdd=(0,05*60*100)/20=15 g
b)mCH3COOZn = 0,05*124=6,2 g