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nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
a, Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=1,2\left(mol\right)\)
\(\Rightarrow m_{HCl}=1,2.36,5=43,8\left(g\right)\)
b, Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\)
a, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.24,79=4,958\left(l\right)\)
\(m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
b, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right);n_{HCl}=\dfrac{365.10\%}{36,5}=1\left(mol\right)\\PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{1}{2}>\dfrac{0,1}{1}\Rightarrow HCldư\\ n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow m_{ZnCl_2}=136.0,1=13,6\left(g\right)\)
a, \(KOH+HCl\rightarrow KCl+H_2O\)
b, \(n_{KOH}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(n_{KCl}=n_{KOH}=0,2\left(mol\right)\Rightarrow m_{KCl}=0,2.74,5=14,9\left(g\right)\)
c, \(n_{HCl}=n_{KOH}=0,2\left(mol\right)\Rightarrow m_{HCl}=0,2.36,5=7,3\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{7,3}{40\%}=18,25\left(g\right)\)
Ta có: \(n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
____0,5____________0,5 (mol)
a, \(m_{CuCl_2}=0,5.135=67,5\left(g\right)\)
b, Có: m dd sau pư = mCuO + m dd HCl = 40 + 200 = 240 (g)
\(\Rightarrow C\%_{CuCl_2}=\dfrac{67,5}{240}.100\%=28,125\%\)
Bạn tham khảo nhé!
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ n_{HCl}=\dfrac{25,55}{36,5}=0,7\left(mol\right)\\a. 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ b.Vì:\dfrac{0,2}{2}< \dfrac{0,7}{6}\\ \Rightarrow HCldư\\ n_{HCl\left(dư\right)}=0,7-\dfrac{6}{2}.0,2=0,1\left(mol\right)\\ n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\\ n_{H_2}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\ m_{H_2}=0,3.2=0,6\left(g\right)\\ m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\\ m_{AlCl_3}=133,5.0,2=26,7\left(g\right)\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{2}>\dfrac{0,2}{6}\), ta được Al dư.
Theo PT: \(n_{AlCl_3}=\dfrac{1}{3}n_{HCl}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=\dfrac{1}{15}.133,6=8,9\left(g\right)\)
\(n_{Al}=\dfrac{5,4}{27}=0,2mol\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{Al}=n_{AlCl_3}=0,2mol\\ m_{AlCl_3}=0,2.133,5=26,7g\)