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Gọi \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
Mg + 2CH3COOH ---> (CH3COO)2Mg + H2
a---->2a-------------------->a------------------>a
Zn + 2CH3COOH ---> (CH3COO)2Zn + H2
b---->2b------------------->b------------------>b
=> \(\left\{{}\begin{matrix}24a+65b=8,9\\a+b=0,2\end{matrix}\right.\Leftrightarrow a=b=0,1\left(mol\right)\)
=> \(\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1.24}{8,9}.100\%=27\%\\\%m_{Zn}=100\%-27\%=73\%\end{matrix}\right.\)
=> \(C\%_{CH_3COOH}=\dfrac{\left(0,1.2+0,1.2\right).60}{200}.100\%=12\%\)
\(m_{dd}=200+8,9-0,2.2=208,5\left(g\right)\)
=> \(\left\{{}\begin{matrix}C\%_{\left(CH_3COO\right)_2Mg}=\dfrac{0,1.142}{208,5}.100\%=6,81\%\\C\%_{\left(CH_3COO\right)_2Zn}=\dfrac{0,1.183}{208,5}.100\%=8,78\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\\n_{Zn}=y\end{matrix}\right.\) ( mol )
\(\rightarrow24x+65y=8,9\left(g\right)\) (1)
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
x 2x x x ( mol )
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\uparrow\)
y 2y y y ( mol )
\(\rightarrow x+y=0,2\left(mol\right)\) (2)
\(\left(1\right);\left(2\right)\rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1.24}{8,9}.100\%=26,96\%\\\%m_{Zn}=100\%-26,96\%=73,04\%\end{matrix}\right.\)
\(m_{CH_3COOH}=\left(2.0,1+2.0,1\right).60=24g\)
\(C\%_{CH_3COOH}=\dfrac{24}{200}.100\%=12\%\)
\(\left\{{}\begin{matrix}m_{\left(CH_3COO\right)_2Mg}=0,1.142=14,2g\\m_{\left(CH_3COO\right)_2Zn}=0,1.183=18,3g\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2.........0.4.........0.2......0.2\)
\(m_{Zn}=0.2\cdot65=13\left(g\right)\Rightarrow m_{ZnO}=14.6-13=1.6\left(g\right)\)
\(\%Zn=\dfrac{13}{14.6}\cdot100\%=89.04\%\)
\(\%ZnO=100\%-89.04\%=10.96\%\)
\(n_{ZnO}=\dfrac{1.6}{81}\approx0.02\left(mol\right)\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
\(0.02........0.04........0.02........0.02\)
\(n_{HCl}=0.4+0.04=0.44\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.44}{0.8}=0.55\left(M\right)\)
Eeeee ngồi tính sang chấn thật nó ra số xấu lần mò hơn 20p chưa biết tính sai chỗ nào
a)Mg+2CH3COOH→Mg(CH3COO)2+H2
Zn+2CH3COOH→Zn(CH3COO)2+H2
nH2=0,3mol
Gọi a và b lần lượt là số mol của Mg và Zn
\(\left\{{}\begin{matrix}24a+65b=11,3\\a+b=0,3\end{matrix}\right.\)
→a=0,2,b=0,1
→mMg=0,2×24=4,8g
→mZn=0,1×65=6,5g
b)%mMg=\(\dfrac{4,8}{11,3}\)×100%=42,48%
%mZn=\(\dfrac{6,5}{11,3}\)×100%=57,52%
c)nCH3COOH=2nMg+2nZn=0,6mol
→mCH3COOH=0,6×60=36g
→C%CH3COOH=\(\dfrac{36}{200}\)×100%=18%
→nMg(CH3COO)2=nMg=0,2mol
→nZn(CH3COO)2=nZn=0,1mol
→mMg(CH3COO)2=0,2×142=28,4g
→mZn(CH3COO)2=0,1×183=18,3g
nH2=nMg+nZn=0,3mol
→mH2=0,6g
→mddmuối=mhỗnhợp+mddCH3COOH−mH2
→mddmuối=11,3+200−0,6=210,7g
→C%Mg(CH3COO)2=\(\dfrac{28,4}{210,7}\)×100%=13,48%
→C%Zn(CH3COO)2=\(\dfrac{18,3}{210,7}\)×100%=8,69%
\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.1.......0.2......................0.1\)
Chất rắn X : Cu
\(m_{Zn}=0.1\cdot65=6.5\left(g\right)\Rightarrow m_{Cu}=19.3-6.5=12.8\left(g\right)\)
\(n_{Cu}=\dfrac{12.8}{64}=0.2\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)
\(2Cu+O_2\underrightarrow{^{^{t^o}}}2CuO\)
\(0.2........0.1\)
\(m_{tăng}=m_{O_2}=0.1\cdot32=3.2\left(g\right)\)
a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow n_{ZnO}=\dfrac{20-0,1\cdot65}{81}=\dfrac{1}{6}\left(mol\right)\)
\(\Rightarrow n_{ZnCl_2}=n_{Zn}+n_{ZnO}=\dfrac{4}{15}\left(mol\right)\)
Mặt khác: \(m_{H_2}=0,1\cdot2=0,2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=119,8\left(g\right)\) \(\Rightarrow C\%_{ZnCl_2}=\dfrac{\dfrac{4}{15}\cdot136}{119,8}\cdot100\%\approx30,27\%\)
c) Giả sử khí là SO2
PTHH: \(Zn+H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}ZnSO_4+SO_2\uparrow+H_2O\)
Theo PTHH: \(n_{SO_2}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,04\left(mol\right)\Rightarrow m_{Zn}=0,04.65=2,6\left(g\right)\)
⇒ mCu = 9 - 2,6 = 6,4 (g)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{2,6}{9}.100\%\approx28,89\%\\\%m_{Cu}\approx71,11\%\end{matrix}\right.\)
a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
b, Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{10,5}.100\%\approx61,9\%\\\%m_{Cu}\approx38,1\%\end{matrix}\right.\)
c, \(n_{H_2SO_4}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)
a) PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
b) \(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
_____0,02<---0,03<---------------------0,03
=> \(\left\{{}\begin{matrix}\%Al=\dfrac{0,02.27}{2,16}.100\%=25\%\\\%Cu=100\%-25\%=75\%\end{matrix}\right.\)
c) mH2SO4 = 0,03.98 = 2,94 (g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{2,94}{200}.100\%=1,47\%\)
Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\\n_{Zn}=y\end{matrix}\right.\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
x 2x x x ( mol )
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
y 2y y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}24x+65y=11,3\\x+y=0,3\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Mg}=0,2.24=4,8g\\m_{Zn}=0,1.65=6,5g\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{4,8}{11,3}.100=42,47\%\\\%m_{Zn}=100\%-42,47\%=57,53\%\end{matrix}\right.\)
\(m_{CH_3COOH}=60.\left(0,2+0,1\right)=18g\)
\(C\%_{CH_3COOH}=\dfrac{18}{200}.100=9\%\)
\(\left\{{}\begin{matrix}m_{\left(CH_3COO\right)_2Mg}=0,2.142=28,4g\\m_{\left(CH_3COO\right)_2Zn}=0,1.183=18,3g\end{matrix}\right.\)
\(m_{ddspứ}=11,3+200-0,3.2=210,7g\)
\(\rightarrow\left\{{}\begin{matrix}C\%_{\left(CH_3COO\right)_2Mg}=\dfrac{28,4}{210,7}.100=13,47\%\\C\%_{\left(CH_3COO\right)_2Zn}=\dfrac{18,3}{210,7}.100=8,68\%\end{matrix}\right.\)