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\(n_{H_2}=\dfrac{2,24}{22,4}=0,1=n_{Zn}\\ n_{ZnO}=\dfrac{14,6-6,5}{81}=0,1mol\\ C\%=\dfrac{0,2\cdot136}{175,6+14,6-0,2}=14,32\%\)
Gọi x, y lần lượt là số mol của Zn và Fe
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
a. PTHH:
Zn + 2HCl ---> ZnCl2 + H2 (1)
Fe + 2HCl ---> FeCl2 + H2 (2)
Theo PT(1): \(n_{H_2}=n_{Zn}=x\left(mol\right)\)
Theo PT(2): \(n_{H_2}=n_{Fe}=y\left(mol\right)\)
=> x + y = 0,3 (*)
Theo đề, ta có: 65x + 56y = 17,7 (**)
Từ (*) và (**), ta có HPT:
\(\left\{{}\begin{matrix}x+y=0,3\\65x+56y=17,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)
=> \(\%_{m_{Zn}}=\dfrac{6,5}{17,7}.100\%=36,72\%\)
\(\%_{m_{Fe}}=100\%-36,72\%=63,28\%\)
b. Ta có: \(n_{hh_{Zn,Fe}}=0,1+0,2=0,3\left(mol\right)\)
Theo PT(1, 2): \(n_{HCl}=2.n_{hh}=2.0,3=0,6\left(mol\right)\)
=> \(m_{HCl}=0,6.36,5=21,9\left(g\right)\)
=> \(C_{\%_{HCl}}=\dfrac{21,9}{200}.100\%=10,95\%\)
C32:
a, \(n_C=\dfrac{2,4}{12}=0,2\left(mol\right)\)
PT: \(C+O_2\underrightarrow{t^o}CO_2\)
Theo PT: \(n_{CO_2}=n_C=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{NaOH}=0,3.1=0,3\left(mol\right)\)
\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=1,5\) → Pư tạo NaHCO3 và Na2CO3
PT: \(CO_2+NaOH\rightarrow NaHCO_3\)
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{NaHCO_3}+n_{Na_2CO_3}=0,2\\n_{NaOH}=n_{NaHCO_3}+2n_{Na_2CO_3}=0,3\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaHCO_3}=0,1\left(mol\right)\\n_{Na_2CO_3}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ mNaHCO3 = 0,1.84 = 8,4 (g)
mNa2CO3 = 0,1.106 = 10,6 (g)
c, \(C_{M_{NaHCO_3}}=C_{M_{Na_2CO_3}}=\dfrac{0,1}{0,3}=\dfrac{1}{3}\left(M\right)\)
Lần sau bạn đăng tách câu hỏi ra nhé.
C31:
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{14,6}.100\%\approx44,52\%\\\%m_{ZnO}\approx55,48\%\end{matrix}\right.\)
c, \(n_{ZnO}=\dfrac{14,6-0,1.65}{81}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,4\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{10\%}=146\left(g\right)\)
Câu 15 :
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,4----->1,2------->0,4------>0,6
\(m_{HCl}=1,2.36,5=43,8\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{43.8.100\%}{25\%}=175,2\left(g\right)\)
\(m_{ddspu}=10,8+175,2-0,6.2=184,8\left(g\right)\)
\(C\%_{AlCl3}=\dfrac{0,4.133,5}{184,8}.100\%=28,9\%\)
\(n_{H_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2.........0.4.........0.2......0.2\)
\(m_{Zn}=0.2\cdot65=13\left(g\right)\Rightarrow m_{ZnO}=14.6-13=1.6\left(g\right)\)
\(\%Zn=\dfrac{13}{14.6}\cdot100\%=89.04\%\)
\(\%ZnO=100\%-89.04\%=10.96\%\)
\(n_{ZnO}=\dfrac{1.6}{81}\approx0.02\left(mol\right)\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
\(0.02........0.04........0.02........0.02\)
\(n_{HCl}=0.4+0.04=0.44\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.44}{0.8}=0.55\left(M\right)\)
Eeeee ngồi tính sang chấn thật nó ra số xấu lần mò hơn 20p chưa biết tính sai chỗ nào
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH :
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,25 0,5 0,25
\(a,m_{Fe}=0,25.56=14\left(g\right)\)
\(b,C_{M\left(HCl\right)}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(m_{HCl}=730.10\%=73\left(g\right)\Rightarrow n_{HCl}=\dfrac{73}{36,5}=2\left(mol\right)\)
\(n_{H_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)\)
→ nHCl > 2nH2 ⇒ HCl dư.
Ta có: 27nAl + 65nZn = 23,8 (1)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Zn}=0,8\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,4\left(mol\right)\\n_{Zn}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{23,8}.100\%\approx45,4\%\\\%m_{Zn}\approx54,6\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{AlCl_3}=n_{Al}=0,4\left(mol\right)\\n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{H_2}=1,6\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=2-1,6=0,4\left(mol\right)\)
Ta có: m dd sau pư = 23,8 + 730 - 0,8.2 = 752,2 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{0,4.133,5}{752,2}.100\%\approx7,1\%\\C\%_{ZnCl_2}=\dfrac{0,2.136}{752,2}.100\%\approx3,62\%\\C\%_{HCl}=\dfrac{0,4.36,5}{752,2}.100\%\approx1,94\%\end{matrix}\right.\)
a) $Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
b)
Theo PTHH : $n_{Zn} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$m_{Zn} = 0,2.65 = 13(gam)$
$m_{ZnO} = 21,1 - 13 = 8,1(gam)$
c) $n_{ZnO} = 0,1(mol)$
Theo PTHH : $n_{HCl} = 2n_{Zn} + 2n_{ZnO} = 0,6(mol)$
$m_{dd\ HCl} = \dfrac{0,6.36,5}{16,6\%} = 132(gam)$
d) $m_{dd\ sau\ pư} = 21,1 + 132 - 0,2.2 = 152,7(gam)$
$n_{ZnCl_2} = n_{Zn} + n_{ZnO} = 0,3(mol)$
$C\%_{ZnCl_2} = \dfrac{0,3.136}{152,7}.100\% = 26,72\%$
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
____0,35_____0,7___________0,35 (mol)
a, \(m_{Zn}=0,35.65=22,75\left(g\right)\)
b, \(C\%_{HCl}=\dfrac{0,7.36,5}{200}.100\%=12,775\%\)
\(a)n_{H_2}=\dfrac{7,84}{22,4}=0,35mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,35 0,7 0,35 0,35
\(m_{Zn}=0,35.65=22,75g\\ b)C_{\%HCl}=\dfrac{0,7.36,5}{200}\cdot100\%=12,775\%\)